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Solid state coordination chemistry: construction of 2D networks and 3D frameworks from phosphomolybdate clusters and binuclear Cu(ii) complexes. The syntheses and structures of [{Cu2(tpypyz)(H2O)2}(Mo5 O15)(HOPO3)2]·nH 2O [n = 2, 3; tpypyz = tetra(2-pyridyl)pyrazine]

✍ Scribed by Burkholder, Eric; Zubieta, Jon


Book ID
120645790
Publisher
Royal Society of Chemistry
Year
2001
Tongue
English
Weight
287 KB
Volume
20
Category
Article
ISSN
1359-7345

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Solid-State Coordination Chemistry of Mo
✍ Randy S. Rarig Jr.; Jon Zubieta 📂 Article 📅 2002 🏛 Elsevier Science 🌐 English ⚖ 217 KB

## IN HONOR OF PROFESSOR GALEN STUCKY ON THE OCCASION OF HIS 65TH BIRTHDAY The hydrothermal reaction of di-2-picolylamine (pca), MoO 3 and NiSO 4 '6H 2 O yielded the bimetallic oxide cluster [{Ni (pca)(H 2 O)} 2 Mo 8 O 26 ]'2H 2 O (1'2H 2 O). Similarly, the reaction of pca, MoO 3 and CuSO 4 '5H 2