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New solids from old clusters: syntheses and structures of [Cu(en)2]2[Mo8O26], [Cu(enMe)2]3[V15O36Cl]·2.5H2O and Cs0.5[Ni(en)2]3[V18O42Cl]·2en·6H2O

✍ Scribed by Jeffrey R.D. DeBord; Robert C. Haushalter; Linda M. Meyer; David J. Rose; Pamela J. Zapf; Jon Zubieta


Book ID
108328529
Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
240 KB
Volume
256
Category
Article
ISSN
0020-1693

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A New Vanadium Oxide Bronze: [NH3(CH2)6N
✍ Thierry Drezen; Marcel Ganne 📂 Article 📅 1999 🏛 Elsevier Science 🌐 English ⚖ 448 KB

A novel mesostructured mixed-valence polyoxovanadate with formula [NH 3 (CH 2 ) 6 NH 3 ] 10 [V 15 O 37 (Cl)] 2 [V 15 O 36 (Cl)] (OH) 3 (H 2 O) 3 was synthesized hydrothermally under autogeneous pressure at 443 K for 5 days from an aqueous mixture of NH 2 (CH 2 ) 6 NH 2 and V 2 O 5 in acidic HCl (1 M