𝔖 Bobbio Scriptorium
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Solid-phase synthesis of two glycopeptides containing the amino acid sequence 5 to 9 of somatostatin

✍ Scribed by Solange Lavielle; Nicolas C. Ling; Roger C. Guillemin


Book ID
108308707
Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
526 KB
Volume
89
Category
Article
ISSN
0008-6215

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The Barton radical decarboxylation on so
✍ Maria Elena Attardi; Maurizio Taddei πŸ“‚ Article πŸ“… 2001 πŸ› Elsevier Science 🌐 French βš– 99 KB

Barton esters were prepared starting from different carboxylic acids loaded on a Wang resin. Light induced fragmentation occurred giving a radical that reacted with CBrCl 3 to give the corresponding bromides, whereas conjugate addition to electron-poor alkenes proved to be less synthetically useful.