𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Solid-Phase Directed Ortho-Lithiation and the Preparation of a Phthalide Library

✍ Scribed by Garibay, Patrick; Vedsø, Per; Begtrup, Mikael; Hoeg-Jensen, Thomas


Book ID
125928747
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
117 KB
Volume
3
Category
Article
ISSN
1520-4766

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Preparation of new chiral borane-protect
✍ Matthias Lotz; Tania Ireland; Katja Tappe; Paul Knochel 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 163 KB 👁 2 views

We have shown that the readily prepared (ferrocenyl)benzylic methyl ethers of type 1 can be ortho-metalated with tert-BuLi with high diastereoselectivity. This reaction has been used to prepare new borane-protected P,N-substituted ferrocenes of type 2 in high diastereomeric and enantiomeric purity.