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Sol–gel entrapped heteronuclear transition metal catalysts

✍ Scribed by Jochanan Blum; Faina Gelman; Raed Abu-Reziq; Irena Miloslavski; Herbert Schumann; David Avnir

Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
182 KB
Volume
19
Category
Article
ISSN
0277-5387

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Chiral Ru-BINAP, Rh-DIOP and Rh-BPPM complexes have been physically entrapped in sol-gel matrices. The resulting materials are recyclable leach-proof catalysts for enantioselective hydrogenation of itaconic acid. Chiral methylsuccinic acid of o.p. up to 78% is obtained. The complexes, including the