Hydrogenation of arenes, alkenes and alk
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Raed Abu-Reziq; Margarita Shenglof; Liza Penn; Tomer Cohen; Jochanan Blum
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Article
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2008
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Elsevier Science
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English
⚖ 379 KB
A sol-gel entrapped 1:3 mixture of [Rh(cod)Cl] 2 and Na[HRu 3 (CO) 11 ] catalyzes the hydrogenation of various unsaturated substrates by two distinguishable mechanisms. Under 13.8 bar H 2 and 20 • C methylated arenes react rapidly to give cycloalkane derivatives. XRD and TEM studies showed that unde