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Sol–gel entrapped Rh2Co2(CO)12: a catalyst precursor for efficient arene hydrogenation

✍ Scribed by Faina Gelman; David Avnir; Herbert Schumann; Jochanan Blum


Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
107 KB
Volume
171
Category
Article
ISSN
1381-1169

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A sol-gel entrapped 1:3 mixture of [Rh(cod)Cl] 2 and Na[HRu 3 (CO) 11 ] catalyzes the hydrogenation of various unsaturated substrates by two distinguishable mechanisms. Under 13.8 bar H 2 and 20 • C methylated arenes react rapidly to give cycloalkane derivatives. XRD and TEM studies showed that unde