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Sodium benzenetellurolate-catalysed selective reduction of aromatic nitro compounds to azoxy compounds

✍ Scribed by Ohe, Kouichi; Takahashi, Hidetaka; Uemura, Sakae; Sugita, Nobuyuki

Book ID
121229141
Publisher
The Royal Society of Chemistry
Year
1988
Tongue
English
Weight
138 KB
Volume
9
Category
Article
ISSN
0022-4936

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Oxygen as moderator in the zinc-mediated
Oxygen as moderator in the zinc-mediated reduction of aromatic nitro to azoxy compounds
✍ Faiz Ahmed Khan; Ch. Sudheer πŸ“‚ Article πŸ“… 2009 πŸ› Elsevier Science 🌐 French βš– 281 KB

A simple and useful protocol for the reduction of nitro arenes to their corresponding azoxy derivatives by employing zinc and NH 4 Cl in a mixture of [bmim][BF 4 ] and water is described. The selective reduction of nitro to azoxy is attributed to the hitherto unknown moderating effect of oxygen on z