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ChemInform Abstract: Cadmium Chloride-Zinc Catalyzed Selective Reduction of Nitro Aromatics to Azoxy Compounds.

โœ Scribed by B. BARUAH; A. BORUAH; D. PRAJAPATI; J. S. SANDHU


Book ID
112037916
Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
27
Category
Article
ISSN
0931-7597

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Oxygen as moderator in the zinc-mediated
โœ Faiz Ahmed Khan; Ch. Sudheer ๐Ÿ“‚ Article ๐Ÿ“… 2009 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 281 KB

A simple and useful protocol for the reduction of nitro arenes to their corresponding azoxy derivatives by employing zinc and NH 4 Cl in a mixture of [bmim][BF 4 ] and water is described. The selective reduction of nitro to azoxy is attributed to the hitherto unknown moderating effect of oxygen on z