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Sodium almagam reduction of 3-bromopropenoic acids: a convenient stereospecific synthesis of [3-3H1] and [3-2H1] acrylic acids

✍ Scribed by D.H.G. Crout; J.A. Corkill

Publisher: Elsevier Science
Year: 1977
Tongue: French
Weight: 178 KB
Volume: 18
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)83507-3

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✦ Synopsis

A variety with isotopic eriopropiolic of methods have been used to synthesise acrylates labelled in the B-position hydrogen. Catalytic deuteration of propiolic esters or hydrogenation of deutesters using the Lindlar catalyst suffered from low stereospecificity and

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