hangige Retlexe, davon 5366 beobachtet ( I > 20(I)), R1 = 0.052, wR2 = 0.142, 420 Parameter. -3 b : triklin P i , u = 13.244(10), b =13.602(11), c =14.421(12) A, = 117.82(6), fl = 96.71(6), y = 104.77(6)", V = 213613) A3, Z = 1, Om,, = 25', 7528 unabhingige Reflexe, davon 61 11 beobachtet ( I > 2u(I
✦ LIBER ✦
Sn6(PR)6], [Sn3(Pr)2, and [Cu24(PR)12] (R = Triorganoisilyl): New Tin and Copper Phosphanediyl Clusters
✍ Scribed by Prof. Dr. Matthias Driess; Dipl.-Chem. Stefan Martin; Dr. Klaus Merz; Dr. Vassili Pintchouk; Dr. Hans Pritzkow; Prog. Dr. Hansjörg Grützmacher; Dr. Martin Kaupp
- Publisher
- John Wiley and Sons
- Year
- 1997
- Tongue
- English
- Weight
- 691 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
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[Sn6(PR)6], [Sn3(PR)2Cl2] und [Cu24(PR)1
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Two new octadecanuclear clusters [Cu 12 Ln 6 ( 3 -OH) 24 (C 5 H 5 NCH 2 CO 2 ) 12 (H 2 O) 18 ( 9 -NO 3 )] (PF 6 ) 10 (NO 3 ) 7 ' 12H 2 O [Ln III ؍ Sm III (1) or Gd III (2)] have been synthesized and characterized by X-ray di4raction. They are isomorphous and crystallize in the triclinic space grou