SmI2-induced ring expansion reactions of alkyl (n+1)-oxobicyclo[n.1.0]alkane-1-carboxylates
β Scribed by Phil Ho Lee; Jukyoung Lee
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- French
- Weight
- 194 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
Alkyl 4-oxocycloalkanecarboxylates were prepared in good yield via ring expansion reactions of alkyl (n+l)-oxobicyclo[n.l.0]alkane-l-carboxylates mediated by SmI2-induced single electron transfer in THF/MeOH.
π SIMILAR VOLUMES
The 147 nm (8.4 eV) photolysis of gaseous C2H51, n-C3H71, and sec-C3H71 was investigated in the presence of and absence of HI. The main overall processes are: These dissociative processes occur mainly as a result of initial cleavage of the weak C-1 bond, followed by decomposition of the internally
## Abstract For Abstract see ChemInform Abstract in Full Text.
## Abstract An efficient procedure is developed via conditions A) (formation of Ξ²βiodoketones) followed by conditions B) in the presence of either TmsCl or TiCl(OβiPr)~3~.
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v