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ChemInform Abstract: A Convenient Transformation of 2-Alkylidenecycloalkanones into Alkyl-Substituted Bicyclo[n.1.0]alkan-1-ols: Application to the Synthesis of Capsaicin.

✍ Scribed by Dzmitry G. Kananovich; Dzmitry M. Zubrytski; Oleg G. Kulinkovich


Publisher
John Wiley and Sons
Year
2010
Weight
63 KB
Volume
41
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

An efficient procedure is developed via conditions A) (formation of β‐iodoketones) followed by conditions B) in the presence of either TmsCl or TiCl(O‐iPr)~3~.


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