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Small rings. 29. Synthesis and ring expansion of vinylazetidines. A synthesis of hydroazocines

✍ Scribed by Hassner, Alfred; Wiegand, Norbert


Book ID
121455913
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
744 KB
Volume
51
Category
Article
ISSN
0022-3263

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Total synthesis of 4-deoxyverrucarol (4), a trichothecane-type sesquiterpene was achieved via two types of ring expansion reaction, 1,2-rearrangement of 18 and palladium mediated ring expansion reaction of 20, as key steps providing a new route to trichothecanes.