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Total synthesis of (±)-4-deoxyverrucarol; a new route to trichothecanes via ring expansion of small ring compounds

✍ Scribed by Hideo Nemoto; Junji Miyata; Masataka Ihara

Publisher: Elsevier Science
Year: 1999
Tongue: French
Weight: 194 KB
Volume: 40
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(99)00047-7

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✦ Synopsis

Total synthesis of 4-deoxyverrucarol (4), a trichothecane-type sesquiterpene was achieved via two types of ring expansion reaction, 1,2-rearrangement of 18 and palladium mediated ring expansion reaction of 20, as key steps providing a new route to trichothecanes.

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