Small-Ring Compounds. XLIII. Formolysis of Substituted Allylcarbinyl Tosylates 1
β Scribed by Servis, Kenneth L.; Roberts, John D.
- Book ID
- 126436001
- Publisher
- American Chemical Society
- Year
- 1965
- Tongue
- English
- Weight
- 961 KB
- Volume
- 87
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
The unusual stability o? the oyolopropyloarbonIu Ion has been studied In many reoent works. (1) The aoid oatalyzed ring opening of unsjmmetrloally substituted epoxldes In Ionizing media has been thought to have an SN-l-like transltlon state, (2) thus the tormolysls of (1,2-epoxy-l-oyolopropylethyl)-
## Abstract 1βHydroxyβ and 1βhalocyclopropyl sulfides can be conveniently prepared starting from cyclopropanone. Cyclopropyl sulfides with halogen or a dimethylsulfonium group in the Ξ±βposition can be transformed into 1βsubstituted cyclopropyl sulfides with a variety of nucleophiles. This means tha