Small-Ring Compounds. XLI. The Formolysis of Allylcarbinyl Tosylate
β Scribed by Servis, Kenneth L.; Roberts, John D.
- Book ID
- 121260901
- Publisher
- American Chemical Society
- Year
- 1964
- Tongue
- English
- Weight
- 579 KB
- Volume
- 86
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
The unusual stability o? the oyolopropyloarbonIu Ion has been studied In many reoent works. (1) The aoid oatalyzed ring opening of unsjmmetrloally substituted epoxldes In Ionizing media has been thought to have an SN-l-like transltlon state, (2) thus the tormolysls of (1,2-epoxy-l-oyolopropylethyl)-
The simple LCAO method with corrections for angle strain indicates that bicyclobutonium cations are likely to be more stable than homoallylic cations. The reverse is predicted to be true for the corresponding free-radical and anionic derivatives. The results are in accord with experiment. THE very