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Small charged rings. X. Expansion of the aziridinium ring by reaction with nitrones

✍ Scribed by Leonard, Nelson J.; Durand, David A.; Uchimaru, Fumihiko

Book ID: 127334817
Publisher: American Chemical Society
Year: 1967
Tongue: English
Weight: 909 KB
Volume: 32
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo01286a068

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Additions and Corrections-Small Charged

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We would like to report a new general ring contraction reaction according to the following scheme (eq. l(a),R = ArSO,): The enol ether la derived from a cyclic ketone is reacted with a suitable aside leading via an intermediate unstable 6'-triazoline & to the ring-contracted imidate ester 3a.

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Additons and Corrections - Small Charged Rings. XV. Kinetics and Stereochemistry of th Ring Expansion Reaciton of 2-Arylaziridinium Salts with Benzaldehyde.

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