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Additions and Corrections-Small Charged Rings. IV. Expansion of the Aziridinium Ring by Reaction with ALdehydes

โœ Scribed by Leonard, Nelson; Kiefer, E; Brady, Leonard


Book ID
127065645
Publisher
American Chemical Society
Year
1965
Tongue
English
Weight
85 KB
Volume
30
Category
Article
ISSN
0022-3263

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The reaction of cyclic enol ethers with
โœ Ronald A. Wohl ๐Ÿ“‚ Article ๐Ÿ“… 1973 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 194 KB

We would like to report a new general ring contraction reaction according to the following scheme (eq. l(a),R = ArSO,): The enol ether la derived from a cyclic ketone is reacted with a suitable aside leading via an intermediate unstable 6'-triazoline & to the ring-contracted imidate ester 3a.