Sm3Cl[SiO4]2: Ein chlorarmes Chloridorthosilicat des Samariums
β Scribed by Corinna Sieke; Thomas Schleid
- Publisher
- John Wiley and Sons
- Year
- 1999
- Tongue
- German
- Weight
- 71 KB
- Volume
- 625
- Category
- Article
- ISSN
- 0372-7874
No coin nor oath required. For personal study only.
β¦ Synopsis
Sm 3 Cl[SiO 4 ] 2 : A Chlorine-poor Chloride Orthosilicate of Samarium
π SIMILAR VOLUMES
THF) 2 Na(Ph 2 N) 2 Sm{N(SiMe 3 ) 2 } 2 ], an Amido Complex of Samarium with a Sandwich-like Coordinated Sodium Ion
Inhaltsu Γ bersicht. Die Sulfidsilicate Sm 4 S 3 [Si 2 O 7 ] und NaSm 9 S 2 [SiO 4 ] 6 erha Γ lt man als hellgelbe, transparente Kristalle bei der Umsetzung von Sm, Sm 2 O 3 , S, SiO 2 und SmCl 3 bzw. NaCl (850 Β°C, 7 d) in entsprechenden molaren Verha Γ ltnissen in evakuierten Quarzglasampullen. Sm
LiNPPh 3 reacts with the cyclooctatetraenide complexes [Ln(C 8 H 8 )Cl(THF) 2 ] 2 of cerium and samarium in tetrahydrofuran solution forming the phosphorane iminato complexes [Ln(C 8 H 8 )Li 3 Cl 2 (NPPh 3 ) 2 (THF) 3 ]. According to crystal structure analyses these complexes show heterocubane struc