Skeletal rearrangement with ring expansion in the simmons-smith reaction of trimethylsiloxymethylenecyclopentanes

✍ Scribed by Ilhyong Ryu; Shinji Murai; Shoji Otani; Noboru Sonoda

• Book ID: 104235959
• Publisher: Elsevier Science
• Year: 1977
• Tongue: French
• Weight: 195 KB
• Volume: 18
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(01)83662-5

✦ Synopsis

Recently cyclopropanation of enol silyl ethers by the use of Simmons-Smith reagent has been reported by this' and the other groups.

2 Cyclopropyl silyl ethers have been proved to be potential synthetic intermediates.