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Six-membered ring-fused thiirene S-oxides. Synthesis, characterization, and reactivity

✍ Scribed by Ando, Wataru; Hanyu, Yukio; Takata, Toshikazu


Book ID
118042386
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
561 KB
Volume
51
Category
Article
ISSN
0022-3263

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## Abstract Cyclopropanecarboxaldehyde (1 a), cyclopropyl methyl ketone (1 b), and cyclopropyl phenyl ketone (1 c) were reacted with [Ni(cod)~2~] (cod=1,5‐cyclooctadiene) and PBu~3~ at 100 °C to give Ξ·^2^‐enonenickel complexes (2 a–c). In the presence of PCy~3~ (Cy=cyclohexyl), 1 a and 1 b reacted