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Synthesis, Characterization and Reactivity of a Novel Six-Membered 1-Isothiocyanato Silatrane

✍ Scribed by Puri, Jugal Kishore; Singh, Gurjaspreet; Duggal, Priya


Book ID
120177620
Publisher
Taylor and Francis Group
Year
2008
Tongue
English
Weight
361 KB
Volume
183
Category
Article
ISSN
1042-6507

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## Abstract Cyclopropanecarboxaldehyde (1 a), cyclopropyl methyl ketone (1 b), and cyclopropyl phenyl ketone (1 c) were reacted with [Ni(cod)~2~] (cod=1,5‐cyclooctadiene) and PBu~3~ at 100 °C to give Ξ·^2^‐enonenickel complexes (2 a–c). In the presence of PCy~3~ (Cy=cyclohexyl), 1 a and 1 b reacted