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Sit Parameters for 1:2 Electrolytes and Correlation with Pitzer Coefficients

✍ Scribed by Francesco Crea; Claudia Foti; Concetta de Stefano; Silvio Sammartano

Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
161 KB
Volume
97
Category
Article
ISSN
0003-4592

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✦ Synopsis

Abstract

The empirical parameters of a two‐parameter SIT equation were determined for some 1:2 electrolytes: chlorides, bromides, iodides, nitrates, perchlorates of alkali earth metals and sulfates of alkali metals. A wide range of ionic strengths (0 < I ≀ 18 mol kg^βˆ’1^) and t = 25 Β°C was considered. Canonical correlation analysis showed quite significant correlations between SIT and Pitzer interaction coefficients for different classes of 1:2 type electrolytes.

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