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Singlet oxygen luminescence as a probe of the stilbene triplet surface

✍ Scribed by A.A. Gorman; M.A.J. Rodgers

Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
352 KB
Volume
120
Category
Article
ISSN
0009-2614

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✦ Synopsis

The quenching of slilbene ~riplrt by oxygen in benzene produces single1 oxygen. O,( 'Ag). with an efficiency or 38~58. This value. logether with the corresponding rate consram. shows Ihal the 02('AB) produced cannor be the consequence or exclusive oxygen quenching or a low concenlralion or planar lrans-niplet in rapid equilibrium wilh the perpendicular form. * Based on the published steady+tate Ka,(= k&lkd) v;llue of 51 P mol-t [ 61 and a 61 ns triplet lifeiimc.

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