Single molecule diffusion and its heterogeneity during the bulk radical polymerization of styrene and methyl methacrylate
✍ Scribed by Stempfle, Beate; Dill, Maren; Winterhalder, Martin J.; Müllen, Klaus; Wöll, Dominik
- Book ID
- 111922537
- Publisher
- The Royal Society of Chemistry
- Year
- 2012
- Tongue
- English
- Weight
- 619 KB
- Volume
- 3
- Category
- Article
- ISSN
- 1759-9954
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## Abstract **Summary:** This work demonstrated the severity of heterogeneity issues with ampoule reactors in bulk atom transfer radical polymerization of methyl methacrylate. The kinetic data of Cu^II^ concentration, monomer conversion, and polymer molecular weight varied from location to location
## Abstract Bulk polymerizations of methyl methacrylate (MMA) at 60°C initiated with 2,2′‐azoisobutyronitrile are influenced by the presence of an organic π‐donor such as tetrathiafulvalene (TTF). Upon addition of TTF, the ratio of weight‐ to number‐average molecular weights __M̄__~w~/__M̄__~n~ are