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Single electron transfer in the Meerwein-Ponndorf-Verley reduction of benzophenone by lithium alkoxides

✍ Scribed by Ashby, E. C.; Argyropoulos, J. N.


Book ID
121872090
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
623 KB
Volume
51
Category
Article
ISSN
0022-3263

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📜 SIMILAR VOLUMES


Evidence for a single electron transfer
✍ E.C. Ashby; J.N. Argyropoulos 📂 Article 📅 1986 🏛 Elsevier Science 🌐 French ⚖ 273 KB

The reduction of benzophenone by lithium alkoxides gives rise to benzophenone ketyl which disappears in a first-order fashion and whose first-order rate constant is approximately equal to the pseudo-first-order rate constant for the formation of the product, benzhydrol.