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Single crystals of isopolyoxometallate(VI) salts as catalysts for the ring-opening polymerization of norbornene

✍ Scribed by Malachy McCann; Deirdre McDonnell; Brian L. Goodall


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
335 KB
Volume
96
Category
Article
ISSN
1381-1169

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πŸ“œ SIMILAR VOLUMES


Catalytic properties of novel chiral pol
✍ Malachy McCann; Andrew J. Beaumont πŸ“‚ Article πŸ“… 1996 πŸ› Elsevier Science 🌐 English βš– 584 KB

Each of the chiral polyoxomolybdate(VI1 salts (R,N 0,02&R jN>,] and (Na),(R ,N )2[Mo,0,,] (R,N = (-I-)cinchonine, t +)-hydroquinidine or (-kquinine). in the presence of the cocatalyst EtAICl,, catalyses the ring-opening metathesis polymerization of norbomene at room temperature. Thr, polynorbomene

Effect of Cocatalysts on the Catalytic A
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## Abstract A series of pentavalent tantalum and niobium complexes with aryloxy ligands was prepared, and their catalytic behavior for the ROMP of norbornene was studied in the presence of an alkylaluminum cocatalyst. Tantalum complexes **1**–**4** showed very high activity for the ROMP of NBE in c

Zinc acetate as a catalyst for the bulk
✍ Ravikumar R. Gowda; Debashis Chakraborty πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 English βš– 366 KB

Zn(OAc) 2 β€’2H 2 O is found to be an effective bulk polymerization catalyst for the ring-opening polymerization of rac-lactide, l-lactide, -caprolactone and ␦-valerolactone. The propensity of polymerizations can be enhanced by performing them in the presence of appropriate amounts of different alcoho

Lithium chloride as catalyst for the rin
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Lithium chloride was found to be an effective and biocompatible catalyst for the ring-opening polymerization of lactide in the presence of hydroxyl-containing compounds. Ethylene glycol (EG) and methyl ␣-D-glucopyranoside (MGlc) were used as multifunctional initiators. The polymerization was carried