Single crystals of isopolyoxometallate(VI) salts as catalysts for the ring-opening polymerization of norbornene
β Scribed by Malachy McCann; Deirdre McDonnell; Brian L. Goodall
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 335 KB
- Volume
- 96
- Category
- Article
- ISSN
- 1381-1169
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Each of the chiral polyoxomolybdate(VI1 salts (R,N 0,02&R jN>,] and (Na),(R ,N )2[Mo,0,,] (R,N = (-I-)cinchonine, t +)-hydroquinidine or (-kquinine). in the presence of the cocatalyst EtAICl,, catalyses the ring-opening metathesis polymerization of norbomene at room temperature. Thr, polynorbomene
## Abstract A series of pentavalent tantalum and niobium complexes with aryloxy ligands was prepared, and their catalytic behavior for the ROMP of norbornene was studied in the presence of an alkylaluminum cocatalyst. Tantalum complexes **1**β**4** showed very high activity for the ROMP of NBE in c
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Lithium chloride was found to be an effective and biocompatible catalyst for the ring-opening polymerization of lactide in the presence of hydroxyl-containing compounds. Ethylene glycol (EG) and methyl β£-D-glucopyranoside (MGlc) were used as multifunctional initiators. The polymerization was carried