Single component ruthenium(IV) catalysts for the ring-opening polymerization of norbornene
β Scribed by Steffen Wache; Wolfgang A. Herrmann; Georg Artus; Oskar Nuyken; Dieter Wolf
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 770 KB
- Volume
- 491
- Category
- Article
- ISSN
- 0022-328X
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## Abstract Ringβopening metathesis polymerization (ROMP) of norbornene catalyzed by niobium(V) __N__,__N__βdialkylcarbamates Nb(O~2~CNR~2~)~5~, __R__β=βEt (**1**), Me (**2**) was studied in the presence of methylaluminoxane (MAO) as a cocatalyst. These novel catalytic systems resulted very active
Optimized ring-opening metathesis polymerization (ROMP) conditions for cyclohexenyl norbornene (CHNB) have been determined. ROMP of CHNB was carried out with ruthenium trichloride hydrate and ruthenium benzylidene catalysts. The effects of mol % catalyst, type of catalyst, use of a dissolution aid (
## Abstract A series of pentavalent tantalum and niobium complexes with aryloxy ligands was prepared, and their catalytic behavior for the ROMP of norbornene was studied in the presence of an alkylaluminum cocatalyst. Tantalum complexes **1**β**4** showed very high activity for the ROMP of NBE in c
FeCl 3 β’6H 2 O, RuCl 3 β’H 2 O and FeCl 2 β’4H 2 O are found to be bulk polymerization catalysts for the ring opening polymerization of -caprolactone, β¦-valerolactone and β€-butyrolactone. These polymerizations can be significantly enhanced by conducting them in the presence of appropriate amounts of d