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Single crystal structure and Mössbauer studies of a new cation-deficient thiospinel: Cu5.47Fe2.9Sn13.1S32

✍ Scribed by G. Garg; S. Bobev; A. Roy; J. Ghose; D. Das; A.K. Ganguli


Book ID
114065919
Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
80 KB
Volume
36
Category
Article
ISSN
0025-5408

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A New Silicon-Doped Cation-Deficient Thi
✍ G Garg; S Bobev; A Roy; J Ghose; D Das; A.K Ganguli 📂 Article 📅 2001 🏛 Elsevier Science 🌐 English ⚖ 300 KB

Starting from pure metals and sulfur in evacuated silica tubes, single crystals of Cu 5.52(8) Si 1.04( 8) ) 1.44 Fe 4 Sn 12 S 32 have been obtained by quenching from 6803C. The above cation-de5cient thiospinel crystallizes in the Fd3 m space group with a ‫؍‬ 10.3322(6) A s . Si doping leads to addit

Crystal Structure, Magnetic, and Mössbau
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\(\mathrm{Cu}_{6} \mathrm{Fe}_{0.9} \mathrm{~V}_{6} \mathrm{O}_{19}\), grown by hydrothermal synthesis, crystallizes in the rhombohedral system, space group \(R \overline{3}\), with \(a=12.9399(8) \AA, c=7.1275(3) \AA(T=293 \mathrm{~K})\), and \(Z=3\). The structure is related to that of so-called \