Starting from pure metals and sulfur in evacuated silica tubes, single crystals of Cu 5.52(8) Si 1.04( 8) ) 1.44 Fe 4 Sn 12 S 32 have been obtained by quenching from 6803C. The above cation-de5cient thiospinel crystallizes in the Fd3 m space group with a ؍ 10.3322(6) A s . Si doping leads to addit
✦ LIBER ✦
Single crystal structure and Mössbauer studies of a new cation-deficient thiospinel: Cu5.47Fe2.9Sn13.1S32
✍ Scribed by G. Garg; S. Bobev; A. Roy; J. Ghose; D. Das; A.K. Ganguli
- Book ID
- 114065919
- Publisher
- Elsevier Science
- Year
- 2001
- Tongue
- English
- Weight
- 80 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0025-5408
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\(\mathrm{Cu}_{6} \mathrm{Fe}_{0.9} \mathrm{~V}_{6} \mathrm{O}_{19}\), grown by hydrothermal synthesis, crystallizes in the rhombohedral system, space group \(R \overline{3}\), with \(a=12.9399(8) \AA, c=7.1275(3) \AA(T=293 \mathrm{~K})\), and \(Z=3\). The structure is related to that of so-called \