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Single crystal nitrogen endor spectra of the four-coordinated low-spin co(II) complex N,N′,ethylenebis(acetylacetonatiminato)Co(II)

✍ Scribed by M. Rudin; E. Jüin; A. Schweiger; Hs.H. Günthard

Publisher: Elsevier Science
Year: 1979
Tongue: English
Weight: 186 KB
Volume: 67
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(79)85181-7

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✦ Synopsis

The hfs and quadrupole tensors of the nitrogen ligands of N,N'-ethylenebis(acetylacetonathninato)Co (II) diluted in a single crystal of the corresponding nickel complex have been determined by electron nuclear double resonance. Weak .x m N = 2 transitions turned out to be useful for the assignment of the spectra. The hfs data support the ground state I vz. 2A2~ which is proposed for four-coordinated low-spin Schiff base complexes of cobalt (II).

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