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Single crystal ERP and powder endor spectra of a five coordinated low-spin Co(II) schiff base complex: N,N'-ethylene-bis (salicylideniminato)-cobalt(II

✍ Scribed by E. Jörin; M. Rudin; A. Schweiger; Hs.H. Gunthard

Publisher: Elsevier Science
Year: 1980
Tongue: English
Weight: 335 KB
Volume: 69
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(80)80043-1

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✦ Synopsis

The magnetx parametersg and AC0 of Cosalenpy doped III a Znsalenpy smgle crystal have been measured and the orientatlons of theu pnnc~pal axes ~th respect to the molecular structure hare been determined.

Furthermore. the hfs and quadrupole tensor of the anal mtrogen were obtamed from powder ENDOR Data are drscusxd usrug weii-established theories.

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Single crystal nitrogen endor spectra of

Single crystal nitrogen endor spectra of the four-coordinated low-spin co(II) complex N,N′,ethylenebis(acetylacetonatiminato)Co(II)

✍ M. Rudin; E. Jüin; A. Schweiger; Hs.H. Günthard 📂 Article 📅 1979 🏛 Elsevier Science 🌐 English ⚖ 186 KB

The hfs and quadrupole tensors of the nitrogen ligands of N,N'-ethylenebis(acetylacetonathninato)Co (II) diluted in a single crystal of the corresponding nickel complex have been determined by electron nuclear double resonance. Weak .x m N = 2 transitions turned out to be useful for the assignment o