Single-Atom Bridged Dinuclear Metal Complexes with Emphasis on Phthalocyanine Systems
โ Scribed by Barbara Floris; Maria Pia Donzello; Claudio Ercolani
- Publisher
- John Wiley and Sons
- Year
- 2004
- Weight
- 52 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0931-7597
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โฆ Synopsis
Abstract
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๐ SIMILAR VOLUMES
## Abstract To explore the metalโmetal interaction and spectroscopic properties, the groundโ and excitedโstate structures of [M~2~(dpm)~2~]^2+^ [M = Ag (2), Cu (3), dpm = bis(diphosphanyl)methane] and their solvated species [M~2~(dpm)~2~]^2+^ยท(MeCN)~2~ were optimized by the MP2 and CIS methods, res
C,,H9N and SnBr, respectively. Ion m/e 179 shifts to m/e 182 in the spectrum of the trideuterated compound ( l a ) , while no shift is observed for m/e 199. Both ions are absent in low energy (12 eV) scans. Ion m/e 199 is formed from the molecular ion by ejection of the metal-ligands followed by ex