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Simultaneous measurement of one-bond and long-range carbon–carbon coupling constants in cembrene

✍ Scribed by L. Ma; P. Bigler

Publisher
John Wiley and Sons
Year
1992
Tongue
English
Weight
606 KB
Volume
30
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

A 1D pulse sequence designed for the selective detection of carbon–carbon connectivities and the measurement of the corresponding coupling constants is presented. The sequence takes advantage of the increased sensitivity and the higher accuracy obtained with multiselective excitation and 1D detection, respectively. The sequence is shown to be a valuable alternative to the popular 2D INADEQUATE experiment in cases where parts, instead of the full, carbon–carbon connectivity matrix are of interest. The sequence is especially useful for the selective measurement of the stereochemically interesting long‐range coupling constants.

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