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Simultaneous determination of transition metals and anions by ion chromatography

โœ Scribed by A.M. Dolgonosov


Book ID
103956455
Publisher
Elsevier Science
Year
1992
Weight
290 KB
Volume
17
Category
Article
ISSN
0923-1137

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โœฆ Synopsis


A method of simultaneous analysis of anions and transition metals in complex form is proposed. Complexes are formed in the separating sorbent under excess quantity of ligand being introduced into the system after conventional separation of sample anions. In order to realize the method, a new central localized sorbent is prepared which has low anion exchange capacity and high cation one. Conditions of separation of mixture contained F-, Cl-, NO2, HPO 2-, Br-, NO3, SO 2-, and Cd 2+, Zn 2+, and Cu 2+ are found. Detection limits and standard deviation are determined.


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The simultaneous determmatlon of SIX metal ions (Cu\*', Zn'+, N?+, Mn'+, Co'+, Pb") by usmg dynamic Ion-exchange chromatography IS proposed The method was apphed to the analysis of human hair after HNO,-HClO, digestion, with detectlon hnuts of ca 1 pg g -' for all the metals exammed, usmg Co as an I