The branching ratio for preionimtion and predksocintion is studied qualitativeIy on the basis of a previously proposed simplisitc classiui probabilistic model of the superexcited states of molecules. The isotope effect is also discussed. ': .' ,-'. ' '.
Simplistic classical probabilistic model of superexcited states of molecules
โ Scribed by Hiroki Nakamura
- Publisher
- Elsevier Science
- Year
- 1974
- Tongue
- English
- Weight
- 630 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0009-2614
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๐ SIMILAR VOLUMES
The excess energy dependcrrce of the intersystems crossing rate constant for hrSe isohted moIecu!es is studied assuming rapid redistribution of vibrational energy after excitation. Exponential increase of therJfe:-constant is predieted for hge separation between the initial singlet and the final tri
Some o +x\* supcrexcited states of the trans-l,3-butadiene molcule have been calculated in order to establish them as possible candidates for the 9.52 eV and 11.04 eV transitions observed in the electron impact spectra of this molecule. Four states have been solved self-consistently (7a, -r2a,, 2b,