✦ LIBER ✦

Communicating states model for intersystems crossing of isolated molecules

✍ Scribed by S. Fischer; E.W. Schlag; S. Schneider

Publisher: Elsevier Science
Year: 1971
Tongue: English
Weight: 823 KB
Volume: 11
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(71)87008-2

No coin nor oath required. For personal study only.

✦ Synopsis

The excess energy dependcrrce of the intersystems crossing rate constant for hrSe isohted moIecu!es is studied assuming rapid redistribution of vibrational energy after excitation. Exponential increase of therJfe:-constant is predieted for hge separation between the initial singlet and the final triplet states. For small energy separation th rate stays almost constant provided :he transition goes directly via spin-orbit coupling. It inuesscs !incarIy if sphorbit viironic coupling is involved.

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