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Simplification of the Mitsunobu Reaction. Di-p-chlorobenzyl Azodicarboxylate: A New Azodicarboxylate

โœ Scribed by Lipshutz, Bruce H.; Chung, David W.; Rich, Brian; Corral, Ricardo


Book ID
115491169
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
64 KB
Volume
8
Category
Article
ISSN
1523-7060

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Dicyclopentyl azodicarboxylate (DCpAD):
โœ Jian Hai Yang; Li Yan Dai; Xiao Zhong Wang; Ying Qi Chen ๐Ÿ“‚ Article ๐Ÿ“… 2011 ๐Ÿ› Chinese Electronic Periodical Services ๐ŸŒ English โš– 496 KB

Dicyclopentyl azodicarboxylate is introduced as a new azo-reagent which can be conveniently prepared in two steps and be used in the Mitsunobu reaction. Though there are no distinct difference of reactivity between DCpAD and DEAD, the former is a more preferable azo-reagent for its stability.