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Dicyclopentyl azodicarboxylate (DCpAD): A new alternative azo-reagent for the Mitsunobu reaction

✍ Scribed by Jian Hai Yang; Li Yan Dai; Xiao Zhong Wang; Ying Qi Chen

Book ID: 104010598
Publisher: Chinese Electronic Periodical Services
Year: 2011
Tongue: English
Weight: 496 KB
Volume: 22
Category: Article
ISSN: 1001-8417
DOI: 10.1016/j.cclet.2011.03.017

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✦ Synopsis

Dicyclopentyl azodicarboxylate is introduced as a new azo-reagent which can be conveniently prepared in two steps and be used in the Mitsunobu reaction. Though there are no distinct difference of reactivity between DCpAD and DEAD, the former is a more preferable azo-reagent for its stability.

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