๐”– Bobbio Scriptorium
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Simple total synthesis of (+-)-perhydrohistrionicotoxin

โœ Scribed by Corey, E. J.; Arnett, John F.; Widiger, Gary N.


Book ID
115453327
Publisher
American Chemical Society
Year
1975
Tongue
English
Weight
242 KB
Volume
97
Category
Article
ISSN
0002-7863

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๐Ÿ“œ SIMILAR VOLUMES


Furans in synthesis.7. A formal total sy
โœ Steven P Tanis; Lisa A Dixon ๐Ÿ“‚ Article ๐Ÿ“… 1987 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 235 KB

## &&&: A formal total synthesis of (+/-)-perhydrohistrionicotoxin is reported. This sequence utilizes a regiospecific &acyliminium ion initiated-furan terminated cyclization to construct the desired azaspiro[55]undecane ring system.

Formal synthesis of (ยฑ)-perhydrohistrion
โœ Andrew B. Holmes; Keith Russell; Edward S. Stern; Michael E. Stubbs; Nicholas K. ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 210 KB

Surnarg: The syntheses of 1-benzyl-7-butyl-l-azaspirocyclo[5.5lundec-7-ene ( ) [a formal precursor of perhydrohistrionicotoxin (2)] and the thermodynamically preferred 18 xocyclic isomer ( ) in six steps from the readily available N-benzyloxycarbonyl-lo-amino-8 ' -octalin -(5) are reported.