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Furans in synthesis.7. A formal total synthesis of (+/−)-perhydrohistrionicotoxin

✍ Scribed by Steven P Tanis; Lisa A Dixon

Publisher: Elsevier Science
Year: 1987
Tongue: French
Weight: 235 KB
Volume: 28
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)95450-9

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✦ Synopsis

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A formal total synthesis of (+/-)-perhydrohistrionicotoxin is reported. This sequence utilizes a regiospecific &acyliminium ion initiated-furan terminated cyclization to construct the desired azaspiro[55]undecane ring system.

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