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Simple Synthesis of CpNi(NHC)Cl Complexes (Cp = Cyclopentadienyl; NHC = N-Heterocyclic Carbene)

✍ Scribed by Kelly, Roy A.; Scott, Natalie M.; Díez-González, Silvia; Stevens, Edwin D.; Nolan, Steven P.


Book ID
120243738
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
136 KB
Volume
24
Category
Article
ISSN
0276-7333

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N-Heterocyclic Carbene Functionalized Ir
✍ Arjan T. Termaten; Marius Schakel; Andreas W. Ehlers; Martin Lutz; Anthony L. Sp 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 153 KB 👁 1 views

## Abstract The novel phosphinidene complex [Cp\*(NHC)IrPMes\*] (**3**; NHC=1,3‐diisopropyl‐4,5‐dimethylimidazol‐2‐ylidene) was prepared in high yield from [Cp\*(NHC)IrCl~2~] (**2**) and [LiPHMes\*]**⋅**3 THF. It represents the first example of an NHC ligated transition metal phosphinidene complex