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Synthetic and Structural Studies of (NHC)Pd(allyl)Cl Complexes (NHC = N-heterocyclic carbene)

✍ Scribed by Viciu, Mihai S.; Marion, Nicolas; Stevens, Edwin D.; Cavallo, Luigi; Nolan, Steven P.; Navarro, Oscar; Germaneau, Romain F.; Kelly, Roy A.; Sommer, William

Book ID
111900253
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
223 KB
Volume
23
Category
Article
ISSN
0276-7333

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A General Synthetic Route to Mixed NHC–P
A General Synthetic Route to Mixed NHC–Phosphane Palladium(0) Complexes (NHC=N-Heterocyclic Carbene)
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## Abstract Mixed NHC–phosphane palladium(0) complexes [(NHC)Pd(PR~3~)] (NHC: N‐heterocyclic carbene) are synthesized directly from commercially available reagents, with the possibility to tune the nature of both the NHC and the phosphane. Reaction of [(NHC)Pd(allyl)Cl] (palladium source) and PR~3~