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Simple syntheses of dl-phyllostine, dl-epoxydon and dl-epiepoxydon

โœ Scribed by Akitami Ichihara; Ryoji Kimura; Kengo Oda; Sadao Sakamura


Book ID
104225671
Publisher
Elsevier Science
Year
1976
Tongue
French
Weight
193 KB
Volume
17
Category
Article
ISSN
0040-4039

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โœฆ Synopsis


In the series of research works aimed at the synthesis of highly oxygenated cyclohexane derivatives '), we reported the synthesis of dl-phyllostine (A)

and an antitumor compound, dl-epoxydon 2)(@' However, the previous synthesis was started from rather expensive gentisic acid and involved non-stereoselective multi-step reactions.


๐Ÿ“œ SIMILAR VOLUMES


Regiospecific syntheses of dl-phyllostin
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Previously we reported a synthesis of 3 dl-phyllostine 1 and conversion of epoxydonl) 1 (phyllosino13)) t o other minor constituents isolated from culture broth of phyllosticta sp 4) . In this communication we would like to describe regiospecific syntheses of dl-phyllostine 1 and dl-epoxydon 9 (phyl

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