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Simple methods for the preparation of N-triflyl guanidines and the structure of compounds with the CF3SO2NCN fragment

✍ Scribed by Bagrat A. Shainyan; Ljudmila L. Tolstikova; Uwe Schilde


Book ID
113711612
Publisher
Elsevier Science
Year
2012
Tongue
English
Weight
600 KB
Volume
135
Category
Article
ISSN
0022-1139

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Homogeneous catalysis. Use of the [TiCp2
✍ T.Keith Hollis; N.P. Robinson; John Whelan; B. Bosnich πŸ“‚ Article πŸ“… 1993 πŸ› Elsevier Science 🌐 French βš– 297 KB

## The effectiveness of the [TiCp2(CF$O3)2] catalyst for the Sakurai reaction has been exploredfor a variety of allylic silanes reacting with orthoesters, ace&, ketals, aldehydes and ketones. The Sakurai reaction (eqs 1.2) is promoted by a variety of Lewis acid@ including TiQ, Alc13, BF3, MesSi R'