Simple and mild procedures for synthesis of benzimidazole derivatives using heterogeneous catalyst systems
โ Scribed by Hashem Sharghi; Omid Asemani; Seyed Mohammad Hossein Tabaei
- Publisher
- Journal of Heterocyclic Chemistry
- Year
- 2008
- Tongue
- English
- Weight
- 363 KB
- Volume
- 45
- Category
- Article
- ISSN
- 0022-152X
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โฆ Synopsis
Abstract
magnified image
TsOH/graphite and N,Nโdimethylaniline/graphite were found to be catalyst systems for condensation reaction of oโphenylendiamine with different aldehydes to form benzimidazole derivatives under mild and simple conditions. The graphite was easily recovered by a simple extraction and could be reused without decrease of activity in the presence of fresh TsOH and N,Nโdimethylaniline.
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## Abstract magnified image A Direct one step synthesis of various benzimidazoles from 3,4โdiaminotoluene and benzaldehydes is described using TCCA as the oxidant. The salient features of this method include simple procedure, mild condition, no waste products, easy separation, low reaction times a
## Abstract For Abstract see ChemInform Abstract in Full Text.