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Simple and efficient synthesis of 5-substituted 1-H-tetrazoles using metal-modified clay catalysts

✍ Scribed by Alireza Najafi Chermahini; Abbas Teimouri; Ali Moaddeli

Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
88 KB
Volume
22
Category
Article
ISSN
1042-7163

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✦ Synopsis

Abstract

The synthesis of 5‐substituted 1‐H‐tetrazoles based on reaction of a series of aromatic nitriles with sodium azide was investigated. The reaction was catalyzed by modified montmorillonite K‐10 including Cu^2+^, Fe^3+^, Ni^2+^, and Zn^2+^ metal ions. The best results obtained by Mont‐K10‐Cu catalyst. The catalysts were reused several times without loss of their activity. The present procedure offers advantages such as a shorter reaction time, simple workup, recovery, and reusability of the catalyst. Β© 2011 Wiley Periodicals, Inc. Heteroatom Chem 22:168–173, 2011; View this article online at wileyonlinelibrary.com. DOI 10.1002/hc.20672

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