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Simple and Advantageneous Stereoselective Synthesis of ( Z )-Allyl Phosphonates Starting from Baylis–Hillman Adducts

✍ Scribed by Das, Biswanath; Bhunia, Nisith; Damodar, Kongara


Book ID
120462856
Publisher
Taylor and Francis Group
Year
2012
Tongue
English
Weight
279 KB
Volume
42
Category
Article
ISSN
0039-7911

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📜 SIMILAR VOLUMES


ChemInform Abstract: Facile Stereoselect
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Treatment of Baylis-Hillman adducts 1 with bromo(dimethyl)sulfonium bromide, Br(Me 2 )S + Br À , in MeCN was found to stereoselectively afford (Z)-and (E)-allyl bromides 2. The reaction is rapid at room temperature, high-yielding, and highly stereoselective.

Stereoselective synthesis of trisubstitu
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## Abstract A series of trisubstituted alkenes containing (__Z__)‐allylthio moieties as key structural units, that is, sodium (__Z__)‐allyl thiosulfates, symmetrical di(__Z__‐allyl) sulfides, and di(__Z__‐allyl) disulfides, unsymmetrical diallyl sulfides were prepared in moderate to good yields via