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Simple Alumination Reactions of Pentamethylcyclopentadienyl Ligands in the Decamethylzirconocene−Bis(trimethylsilyl)acetylene Complex Cp* 2 Zr(η 2 -Me 3 SiC 2 SiMe 3 )

✍ Scribed by Burlakov, Vladimir V.; Arndt, Perdita; Baumann, Wolfgang; Spannenberg, Anke; Rosenthal, Uwe


Book ID
126957929
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
94 KB
Volume
25
Category
Article
ISSN
0276-7333

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The Influence of the Ligands Cp*(η5-C5Me
✍ Paul-Michael Pellny; Vladimir V. Burlakov; Wolfgang Baumann; Anke Spannenberg; U 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 German ⚖ 213 KB 👁 1 views

The reactions of the bis(trimethylsilyl)acetylene permethylmetallocene complexes Cp 2 M(g 2 -Me 3 SiC 2 SiMe 3 ) (M = Ti (1), M = Zr (2)) with H 2 O and CO 2 were studied and compared to those of the corresponding metallocene complexes Cp 2 M(L)(g 2 -Me 3 SiC 2 SiMe 3 ) (M = Ti (3), L = ± ; M = Zr,