Simple access to highly enantiomerically enriched (S)-3-methyl-1-pentanol, (S)-3-methyl-1-pentene, (2R,3S)-2-deuterio-3-methyl-1-pentanol and (2S,3S)-3-methyl-2-pentanol from natural (L)-isoleucine
✍ Scribed by Schurig, Volker; Leyrer, Ulrich; Wistuba, Dorothee
- Book ID
- 120527519
- Publisher
- American Chemical Society
- Year
- 1986
- Tongue
- English
- Weight
- 502 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0022-3263
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📜 SIMILAR VOLUMES
The title compound, C 14 H 16 N 2 O 2 , was obtained from the reaction between S-tryptophan methyl ester hydrochloride and acetaldehyde. The molecule adopts a trans configuration, with the methyl and methoxycarbonyl groups located on opposite sides of the central tetrahydro--carboline unit. Bifurcat
The relative con®guration of the title compound, C 18 H 27 NO 4 , was determined as being R,S,S,S. There are three crystallographically independent molecules in the asymmetric unit, which show only slight conformational differences. Molecules in the crystal structure are connected by hydrogen bonds