The metal-versus-semiconductor behavior of ruthenium pyrochlores A 2 Ru 2 O 7؊y was examined by calculating their electronic band structures. This behavior is explained in terms of the Mott-Hubbard mechanism of electron localization. The width of the t 2g -block bands of A 2 Ru 2 O 7؊y increases wit
✦ LIBER ✦
Similarities and Differences in the Structural and Electronic Properties of Ruthenium and Iridium PyrochloresA2M2O7−y(M=Ru, Ir)
✍ Scribed by H.-J. Koo; M.-H. Whangbo; B.J. Kennedy
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- English
- Weight
- 269 KB
- Volume
- 136
- Category
- Article
- ISSN
- 0022-4596
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